Dalton (unit)
| dalton (unified atomic mass unit) | |
|---|---|
| Unit of | mass |
| Symbol | Da or u |
| Named after | John Dalton |
| Conversions | |
| 1 Da or u in ... | ... is equal to ... |
| kg | 1.66053906892(52)×10−27 |
| mu | 1 |
| MeV/c2 | 931.49410372(29) |
The dalton or unified atomic mass unit (symbols: Da or u, respectively) is a unit of mass defined as 1/12 of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at rest.[1][2][3] It is a non-SI unit accepted for use with SI. The word "unified" emphasizes that the definition was accepted by both IUPAP and IUPAC.[4] The atomic mass constant, denoted mu, is defined identically. Expressed in terms of ma(12C), the atomic mass of carbon-12: mu = ma(12C)/12 = 1 Da.[5] The dalton's numerical value in terms of the fixed-h kilogram is an experimentally determined quantity that, along with its inherent uncertainty, is updated periodically. The 2022 CODATA recommended value of the atomic mass constant expressed in the SI base unit kilogram is:
mu = 1.66053906892(52)×10−27 kg.[6]
As of June 2025, the value given for the dalton (1 Da = 1 u = mu) in the SI Brochure is still listed as the 2018 CODATA recommended value:
1 Da = mu = 1.66053906660(50)×10−27 kg.[7]
This was the value used in the calculation of g/Da, the traditional definition of the Avogadro number, g/Da = 6.022 140 762 081 123 . . . × 1023, which was then rounded to 9 significant figures and fixed at exactly that value for the 2019 redefinition of the mole.
The value serves as a conversion factor of mass from daltons to kilograms, which can easily be converted to grams and other metric units of mass. The 2019 revision of the SI redefined the kilogram by fixing the value of the Planck constant (h), improving the precision of the atomic mass constant expressed in SI units by anchoring it to fixed physical constants. Although the dalton remains defined via carbon-12, the revision enhances traceability and accuracy in atomic mass measurements.
The mole is a unit of amount of substance used in chemistry and physics, such that the mass of one mole of a substance expressed in grams (i.e., the molar mass in g/mol or kg/kmol) is numerically equal to the average mass of an elementary entity of the substance (atom, molecule, or formula unit) expressed in daltons. For example, the average mass of one molecule of water is about 18.0153 Da, and the mass of one mole of water is about 18.0153 g. A protein whose molecule has an average mass of 64 kDa would have a molar mass of 64 kg/mol. However, while this equality can be assumed for practical purposes, it is only approximate, because of the 2019 redefinition of the mole.[8][1]
- ^ a b Cite error: The named reference
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- ^ "2022 CODATA Value: atomic mass constant". The NIST Reference on Constants, Units, and Uncertainty. NIST. May 2024. Retrieved 2024-05-18.
- ^ The International System of Units (9th(v3.01) ed.), International Bureau of Weights and Measures, August 2024, p. 145, ISBN 978-92-822-2272-0
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