Cyclopropane

Cyclopropane[1]
Names
Preferred IUPAC name
Cyclopropane[2]
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.000.771
KEGG
UNII
UN number 1027
  • InChI=1S/C3H6/c1-2-3-1/h1-3H2 Y
    Key: LVZWSLJZHVFIQJ-UHFFFAOYSA-N Y
  • InChI=1/C3H6/c1-2-3-1/h1-3H2
    Key: LVZWSLJZHVFIQJ-UHFFFAOYAL
  • C1CC1
Properties
C3H6
Molar mass 42.08 g/mol
Appearance Colorless gas
Odor Sweet, ethereal
Density 1.879 g/L (1 atm, 0 °C)
680 g/L (liquid)
Melting point −128 °C (−198 °F; 145 K)
Boiling point −32.9 °C (−27.2 °F; 240.2 K)
502 mg/L
Vapor pressure 640 kPa (20 °C)
1350 kPa (50 °C)
Acidity (pKa) ~46
Magnetic susceptibility (χ)
−39.9·10−6 cm3/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Highly flammable
Asphyxiant
GHS labelling:
Danger
NFPA 704 (fire diamond)
1
4
0
SA
495 °C (923 °F; 768 K)
Explosive limits 2.4 % (lower)
10.4 % (upper)
Safety data sheet (SDS) Air Liquide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Cyclopropane is the cycloalkane with the molecular formula (CH2)3, consisting of three methylene groups (CH2) linked to each other to form a triangular ring. The small size of the ring creates substantial ring strain in the structure. Cyclopropane itself is mainly of theoretical interest, but many cyclopropane derivatives are of commercial or biological significance.[3]

Cyclopropane was used as a clinical inhalational anesthetic from the 1930s through the 1980s. The substance's high flammability poses a risk of fire and explosions in operating rooms due to its tendency to accumulate in confined spaces, as its density is higher than that of air.

  1. ^ Merck Index, 11th Edition, 2755.
  2. ^ "Front Matter". Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 137. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
  3. ^ Faust, Rüdiger (2001). "Fascinating Natural and Artificial Cyclopropane Architectures". Angewandte Chemie International Edition. 40 (12): 2251–2253. doi:10.1002/1521-3773(20010618)40:12<2251::AID-ANIE2251>3.0.CO;2-R. PMID 11433485.