Iodoform

Iodoform
Names
	Preferred IUPAC name Triiodomethane
	Other names Iodoform; Carbon hydride triiodide; Carbon triiodide;
Identifiers
CAS Number	75-47-8 ;
3D model (JSmol)	Interactive image;
Beilstein Reference	1697010
ChEBI	CHEBI:37758 ;
ChEMBL	ChEMBL1451116 ;
ChemSpider	6134 ;
ECHA InfoCard	100.000.795
EC Number	200-874-5;
KEGG	D01910 ;
MeSH	iodoform
PubChem CID	6374;
RTECS number	PB7000000;
UNII	KXI2J76489 ;
CompTox Dashboard (EPA)	DTXSID4020743 ;
	InChI InChI=1S/CHI3/c2-1(3)4/h1H Key: OKJPEAGHQZHRQV-UHFFFAOYSA-N ;
	SMILES IC(I)I;
Properties
Chemical formula	CHI3
Molar mass	393.732 g·mol−1
Appearance	Pale, light yellow, opaque crystals
Odor	Saffron-like
Density	4.008 g/cm3
Melting point	119 °C (246 °F; 392 K)
Boiling point	218 °C (424 °F; 491 K)
Solubility in water	100 mg/L
Solubility in diethyl ether	136 g/L
Solubility in acetone	120 g/L
Solubility in ethanol	78 g/L
log P	3.118
Henry's law; constant (kH)	3.4 μmol·Pa−1·kg−1
Magnetic susceptibility (χ)	−117.1·10−6 cm3/mol
Structure
Crystal structure	Hexagonal
Molecular shape	Tetrahedral at C
Thermochemistry
Heat capacity (C)	157.5 J/(K·mol)
Std enthalpy of; formation (ΔfH⦵298)	180.1 – 182.1 kJ/mol
Std enthalpy of; combustion (ΔcH⦵298)	−716.9 – −718.1 kJ/mol
Pharmacology
ATC code	D09AA13 (WHO)
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P280, P305+P351+P338
NFPA 704 (fire diamond)	2 1 1
Flash point	204 °C (399 °F; 477 K)
	Lethal dose or concentration (LD, LC):
LD50 (median dose)	355 mg/kg (oral, rat); 1180 mg/kg (dermal, rat); 1.6 mmol/kg(s.c., mouse);
	NIOSH (US health exposure limits):
PEL (Permissible)	none
REL (Recommended)	0.6 ppm (10 mg/m3)
IDLH (Immediate danger)	N.D.
Related compounds
Related compounds	Methyl iodide; Diiodomethane; Carbon tetraiodide; Fluoroform; Chloroform; Bromoform;
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Iodoform (also known as triiodomethane) is the organoiodine compound with the chemical formula CHI₃. It is a pale yellow, crystalline, volatile substance, with a penetrating and distinctive odor (in older chemistry texts, the smell is sometimes referred to as that of hospitals, where the compound is still commonly used) and, analogous to chloroform, sweetish taste. It is occasionally used as a disinfectant.

^ "Front Matter". Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 661. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4. The retained names 'bromoform' for HCBr₃, 'chloroform' for HCCl₃, and 'iodoform' for HCI₃ are acceptable in general nomenclature. Preferred IUPAC names are substitutive names.
^ "Iodoform".
^ ^a ^b ^c ^d ^e ^f ^g Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
^ ^a ^b ^c NIOSH Pocket Guide to Chemical Hazards. "#0343". National Institute for Occupational Safety and Health (NIOSH).
^ Merck Index, 12 Edition, 5054

[iupac2013-1] "Front Matter". Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 661. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4. The retained names 'bromoform' for HCBr₃, 'chloroform' for HCCl₃, and 'iodoform' for HCI₃ are acceptable in general nomenclature. Preferred IUPAC names are substitutive names.

[pubchem-2] "Iodoform".

[GESTIS-3] ^ ^a ^b ^c ^d ^e ^f ^g Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health

[PGCH-4] NIOSH Pocket Guide to Chemical Hazards. "#0343". National Institute for Occupational Safety and Health (NIOSH).

[Merck-5] Merck Index, 12 Edition, 5054

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