Acid–base reaction

In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base. It can be used to determine pH via titration. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.

Their importance becomes apparent in analyzing acid–base reactions for gaseous or liquid species, or when acid or base character may be somewhat less apparent. The first of these concepts was provided by the French chemist Antoine Lavoisier, around 1776.[1]

It is important to think of the acid–base reaction models as theories that complement each other.[2] For example, the current Lewis model has the broadest definition of what an acid and base are, with the Brønsted–Lowry theory being a subset of what acids and bases are, and the Arrhenius theory being the most restrictive. Arrhenius describe an acid as a compound that increases the concentration of hydrogen ions(H³O+ or H+) in a solution. A base is a substance that increases the concentration of hydroxide ions(H-) in a solution. However Arrhenius definition only applies to substances that are in water.

  1. ^ Miessler & Tarr 1991, p. 166 – Table of discoveries attributes Antoine Lavoisier as the first to posit a scientific theory in relation to oxyacids.
  2. ^ Paik, Seoung-Hey (2015). "Understanding the Relationship Among Arrhenius, Brønsted–Lowry, and Lewis Theories". Journal of Chemical Education. 92 (9): 1484–1489. Bibcode:2015JChEd..92.1484P. doi:10.1021/ed500891w.